Listar columnas con índices en PostgreSQL

Crea algunos datos de prueba...

create table test (a int, b int, c int, constraint pk_test primary key(a, b));
create table test2 (a int, b int, c int, constraint uk_test2 unique (b, c));
create table test3 (a int, b int, c int, constraint uk_test3b unique (b), constraint uk_test3c unique (c),constraint uk_test3ab unique (a, b));

Lista de índices y columnas indexadas:

select
    t.relname as table_name,
    i.relname as index_name,
    a.attname as column_name
from
    pg_class t,
    pg_class i,
    pg_index ix,
    pg_attribute a
where
    t.oid = ix.indrelid
    and i.oid = ix.indexrelid
    and a.attrelid = t.oid
    and a.attnum = ANY(ix.indkey)
    and t.relkind = 'r'
    and t.relname like 'test%'
order by
    t.relname,
    i.relname;

 table_name | index_name | column_name
------------+------------+-------------
 test       | pk_test    | a
 test       | pk_test    | b
 test2      | uk_test2   | b
 test2      | uk_test2   | c
 test3      | uk_test3ab | a
 test3      | uk_test3ab | b
 test3      | uk_test3b  | b
 test3      | uk_test3c  | c

Enrolle los nombres de las columnas:

select
    t.relname as table_name,
    i.relname as index_name,
    array_to_string(array_agg(a.attname), ', ') as column_names
from
    pg_class t,
    pg_class i,
    pg_index ix,
    pg_attribute a
where
    t.oid = ix.indrelid
    and i.oid = ix.indexrelid
    and a.attrelid = t.oid
    and a.attnum = ANY(ix.indkey)
    and t.relkind = 'r'
    and t.relname like 'test%'
group by
    t.relname,
    i.relname
order by
    t.relname,
    i.relname;

 table_name | index_name | column_names
------------+------------+--------------
 test       | pk_test    | a, b
 test2      | uk_test2   | b, c
 test3      | uk_test3ab | a, b
 test3      | uk_test3b  | b
 test3      | uk_test3c  | c