Puede usar la función PARSENAME de la siguiente manera:
with address as(
select '192.168.1.1' as IpAddress
Union
select '192.168.1.2' as IpAddress
Union
select '192.168.1.3' as IpAddress
)
SELECT PARSENAME(IpAddress,4) as first,
PARSENAME(IpAddress,3) as second,
PARSENAME(IpAddress,2) as third,
PARSENAME(IpAddress,1) as fourth,
FROM address
La función PARSENAME devuelve la parte especificada de un nombre de objeto.