T-SQL recorriendo la columna de datos XML para derivar un conjunto único de rutas

El enfoque obsoleto con FROM OPENXML podría ser una opción aquí. Consulta esta respuesta .

En este enlace encontrará una función que John Cappelletti publica de vez en cuando, que destruirá cualquier XML (créditos debajo del código de la función).

Pero no estoy seguro de lo que realmente estás tratando de lograr... ¿Por qué necesitas el camino? Si está interesado en los valores de todos los nodos de destino, puede hacer algo como esto (búsqueda profunda con // no necesita el XPath exacto )

 SELECT t.value(N'(text())[1]','nvarchar(max)')
 FROM @xml.nodes('//target') AS A(t);

Si realmente necesitas todo y todo puedes comprobar esto:

CREATE FUNCTION [dbo].[udf-XML-Hier](@XML xml)

Returns Table 
As Return

with  cte0 as ( 
                  Select Lvl       = 1
                        ,ID        = Cast(1 as int) 
                        ,Pt        = Cast(NULL as int)
                        ,Element   = x.value('local-name(.)','varchar(150)')
                        ,Attribute = cast('' as varchar(150))
                        ,Value     = x.value('text()[1]','varchar(max)')
                        ,XPath     = cast(concat(x.value('local-name(.)','varchar(max)'),'[' ,cast(Row_Number() Over(Order By (Select 1)) as int),']') as varchar(max))
                        ,Seq       = cast(1000000+Row_Number() over(Order By (Select 1)) as varchar(max))
                        ,AttData   = x.query('.') 
                        ,XMLData   = x.query('*') 
                  From   @XML.nodes('/*') a(x) 
                  Union  All
                  Select Lvl       = p.Lvl + 1 
                        ,ID        = Cast( (Lvl + 1) * 1024 + (Row_Number() Over(Order By (Select 1)) * 2) as int ) * 10
                        ,Pt        = p.ID
                        ,Element   = c.value('local-name(.)','varchar(150)')
                        ,Attribute = cast('' as varchar(150))
                        ,Value     = cast( c.value('text()[1]','varchar(max)') as varchar(max) ) 
                        ,XPath     = cast(concat(p.XPath,'/',c.value('local-name(.)','varchar(max)'),'[',cast(Row_Number() Over(PARTITION BY c.value('local-name(.)','varchar(max)') Order By (Select 1)) as int),']') as varchar(max) )
                        ,Seq       = cast(concat(p.Seq,' ',10000000+Cast( (Lvl + 1) * 1024 + (Row_Number() Over(Order By (Select 1)) * 2) as int ) * 10) as varchar(max))
                        ,AttData   = c.query('.') 
                        ,XMLData   = c.query('*') 
                  From   cte0 p 
                  Cross  Apply p.XMLData.nodes('*') b(c) 
              )
    , cte1 as (   
                  Select R1 = Row_Number() over (Order By Seq),A.*
                  From  (
                          Select  Lvl,ID,Pt,Element,Attribute,Value,XPath,Seq From cte0
                          Union All
                          Select Lvl       = p.Lvl+1
                                ,ID        = p.ID + Row_Number() over (Order By (Select NULL)) 
                                ,Pt        = p.ID
                                ,Element   = p.Element
                                ,Attribute = x.value('local-name(.)','varchar(150)')
                                ,Value     = x.value('.','varchar(max)')
                                ,XPath     = p.XPath + '/@' + x.value('local-name(.)','varchar(max)')
                                ,Seq       = cast(concat(p.Seq,' ',10000000+p.ID + Row_Number() over (Order By (Select NULL)) ) as varchar(max))
                          From   cte0 p 
                          Cross  Apply AttData.nodes('/*/@*') a(x) 
                        ) A 
               )

Select A.R1
      ,R2  = IsNull((Select max(R1) From cte1 Where Seq Like A.Seq+'%'),A.R1)
      ,A.Lvl
      ,A.ID
      ,A.Pt
      ,A.Element
      ,A.Attribute
      ,A.XPath
      ,Title = Replicate('|---',Lvl-1)+Element+IIF(Attribute='','','@'+Attribute)
      ,A.Value
 From  cte1 A

/*
Source: http://beyondrelational.com/modules/2/blogs/28/posts/10495/xquery-lab-58-select-from-xml.aspx

Taken from John Cappelletti: https://stackoverflow.com/a/42729851/5089204

Declare @XML xml='<person><firstname preferred="Annie" nickname="BeBe">Annabelle</firstname><lastname>Smith</lastname></person>'
Select * from [dbo].[udf-XML-Hier](@XML) Order by R1
*/
GO 

DECLARE @xml XML=
'<log>
  <clients>
   <client>
    <section name ="Apps"> 
     <questions>
      <groupone>
       <question>
        <target>Age</target>
       </question>
       <question>
        <target> Height</target>
       </question>
       <question>
        <target> Weight</target>
       </question>
      </groupone>
      <grouptwo name = "exercise">
       <wording>what is your name</wording>
        <question>
         <id>1</id>
         <target>def</target>
        </question>
      </grouptwo>
     </questions>
    </section>
   </client>
  </clients>
 </log>';

 SELECT * FROM dbo.[udf-XML-Hier](@xml);
GO