ver esta muestra:
create table test (mycol UniqueIdentifier NOT NULL default newid(), name varchar(100))
insert into test (name) values ('Roger Medeiros')
select * from test
para agregar un campo no nulo en una tabla poblada, necesita esto.
alter table test add mycol2 UniqueIdentifier NOT NULL default newid() with values
CREATE UNIQUE NONCLUSTERED INDEX IX_test ON dbo.test
(
mycol
) WITH( STATISTICS_NORECOMPUTE = OFF, IGNORE_DUP_KEY = OFF, ALLOW_ROW_LOCKS = ON, ALLOW_PAGE_LOCKS = ON) ON [PRIMARY]