¿Cómo consultar valores de nodos xml?

SELECT  b.BatchID,
        x.XmlCol.value('(ReportHeader/OrganizationReportReferenceIdentifier)[1]','VARCHAR(100)') AS OrganizationReportReferenceIdentifier,
        x.XmlCol.value('(ReportHeader/OrganizationNumber)[1]','VARCHAR(100)') AS OrganizationNumber
FROM    Batches b
CROSS APPLY b.RawXml.nodes('/CasinoDisbursementReportXmlFile/CasinoDisbursementReport') x(XmlCol);

Demostración:SQLFiddle